|
|
(R)-mandelonitrile + O2 <=> oxo(phenyl)acetonitrile + H2O2
|
1.1.3.49
(R)-mandelonitrile oxidase
|
–
|
|
| |
BRENDA:
BR51731;
BS436664
KEGG:
R11380
MetaCyc:
RXN-17966
|
|
|
|
UDP-glucose + (R)-mandelonitrile <=> prunasin + UDP + H+
|
2.4.1.178
hydroxymandelonitrile glucosyltransferase
2.4.1.354
(R)-mandelonitrile beta-glucosyltransferase
2.4.1.85
cyanohydrin beta-glucosyltransferase
|
–
–
–
|
MK
|
| |
BRENDA:
BR52384;
BS356146
KEGG:
R10638
MetaCyc:
RXN-18095
|
|
|
|
(R)-mandelonitrile <=> cyanide + benzaldehyde
|
4.1.2.10
(R)-mandelonitrile lyase
4.1.2.11
hydroxymandelonitrile lyase
4.1.2.46
aliphatic (R)-hydroxynitrile lyase
4.1.2.47
(S)-hydroxynitrile lyase
4.1.2.B6
|
–
–
–
–
–
|
MK
|
| |
BRENDA:
BR6436;
BS368134
KEGG:
R01767
MetaCyc:
MANDELONITRILE-LYASE-RXN
SABIO-RK:
15344;
1865
|
|
|
|
H2O + (R)-Vicianin <=> vicianose + (R)-mandelonitrile
|
3.2.1.119
vicianin beta-glucosidase
|
–
|
M
|
| |
BRENDA:
BR48184;
BS393819
KEGG:
R03642
MetaCyc:
VICIANIN-BETA-GLUCOSIDASE-RXN
|
|
|
|
amygdalin + H2O <=> (R)-mandelonitrile + gentiobiose
|
3.2.1.119
vicianin beta-glucosidase
|
–
|
|
| |
BRENDA:
BS422219
MetaCyc:
RXN-13610
|
|
|
|
prunasin + H2O <=> (R)-mandelonitrile + D-glucose
|
3.2.1.118
prunasin beta-glucosidase
3.2.1.119
vicianin beta-glucosidase
3.2.1.21
beta-glucosidase
3.2.1.74
glucan 1,4-beta-glucosidase
|
–
–
–
–
|
MK
|
| |
BRENDA:
BR48183;
BS94662
KEGG:
R02558
MetaCyc:
PRUNASIN-BETA-GLUCOSIDASE-RXN
SABIO-RK:
2471
|
|
|
|
(E)-phenylacetaldoxime + reduced_flavodoxin + O2 <=> (R)-mandelonitrile + flavin + 2 H2O
|
1.14.14.44
phenylacetaldehyde oxime monooxygenase
|
–
|
|
| |
BRENDA:
BR52032
KEGG:
R11732
|
|
|
|
phenylacetonitrile + reduced_flavodoxin + O2 <=> (R)-mandelonitrile + flavin + H2O
|
1.14.14.44
phenylacetaldehyde oxime monooxygenase
1.14.14.77
phenylacetonitrile alpha-monooxygenase
|
–
–
|
K
|
| |
BRENDA:
BR52035
KEGG:
R11733
|
|
|
|
(E)-phenylacetaldoxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (R)-mandelonitrile + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.44
phenylacetaldehyde oxime monooxygenase
|
–
|
|
| |
MetaCyc:
RXN-18096
|
|
|
|
phenylacetonitrile + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (R)-mandelonitrile + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.77
phenylacetonitrile alpha-monooxygenase
|
–
|
M
|
| |
MetaCyc:
RXN-18098
|
|
|
|
(R)-mandelonitrile + H2O <=> (R)-mandelamide
|
4.2.1.84
nitrile hydratase
|
–
|
|
| |
BRENDA:
BS444119
|
|
|
|
mandelonitrile + vinyl_acetate <=> (S)-2-acetoxy-2-phenylacetonitrile + (R)-mandelonitrile
|
3.1.1.3
triacylglycerol lipase
|
–
|
|
| |
BRENDA:
BS399193
|
|
